Sorbitol → HCID 86744265、化合物

HRID 1088417

反応式

HRID 1088417 の反応式
[OH:1][CH2:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[C:13]([OH:42])(=[O:41])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40].[Sn]>>[C:13]([OH:42])(=[O:41])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40].[C:13]([OH:42])(=[O:41])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40].[C:13]([OH:42])(=[O:41])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH3:40].[OH:12][CH2:11][C@@H:9]([C@H:7]([C@@H:5]([C@@H:3]([CH2:2][OH:1])[OH:4])[OH:6])[OH:8])[OH:10]

参加物

4

反応物 3

HCID 5780SorbitolHCID 10470Octacosanoic acidHCID 5352426Tin atom

生成物 1

HCID 86744265HCID 86744265、化合物

反応条件

温度
100 °C

実験手順

41.1 g sorbitol (0.226 mole), 271.1 g montanic acid (0.678 mole) and 0.4 g tin powder were heated to 200° C. as in Example 1 with application of a gentle vacuum. The vacuum was increased to 15 mbar over a period of 14 h, by which time the acid value had fallen to 5. After cooling to 100° C., the product was filtered, giving a brown hard wax having a dropping point of 78° C.

後処理

  1. temperatureThe vacuum was increased to 15 mbar over a period of 14 h, by which time the acid value
  2. filtrationthe product was filtered
  3. customgiving a brown hard wax
  4. customa dropping point of 78° C.

出典と根拠

ORDレコード
ord-ad12c830b0954be2b0ad1e72ee90f6ba
出典データセット
uspto-grants-1990_10
特許番号
US04962145

関連ノート

読み込み中…