Methyl iodide → HCID 15008680、化合物
反応式
[Br:1][C:2]1[CH:20]=[C:19]([N+:21]([O-:23])=[O:22])[CH:18]=[CH:17][C:3]=1[NH:4][C:5](=[O:16])[C:6]([F:15])([C:11]([F:14])([F:13])[F:12])[C:7]([F:10])([F:9])[F:8].CI.[C:26](=O)([O-])[O-].[K+].[K+]>CC(C)=O>[CH3:26][N:4]([C:5](=[O:16])[C:6]([F:15])([C:11]([F:12])([F:13])[F:14])[C:7]([F:8])([F:9])[F:10])[C:3]1[CH:17]=[CH:18][C:19]([N+:21]([O-:23])=[O:22])=[CH:20][C:2]=1[Br:1]参加物
5
実験手順
2'-Bromo-4'-nitro-2,3,3,3-tetrafluoro-2-(trifluoromethyl)propionanilide was reacted with methyl iodide, in acetone and in the presence of potassium carbonate, yielding N-methyl-2'-bromo-4'-nitro-2,3,3,3-tetrafluoro-2-(trifluoromethyl)propionanilide, an oil, yield 70% (>99% branched isomer).
出典と根拠
- ORDレコード
- ord-f55f15dd43e84910953823d075e161fb
- 出典データセット
- uspto-grants-1990_10
- 特許番号
- US04962284
反応ノート
読み込み中…