Toluene → HCID 23693908、化合物

HRID 1089642ノート

反応式

HRID 1089642 の反応式
C(OC)(=O)C1C=CC(C([O-])=O)=CC=1.[K+:14].[C:15]([O:29]CCC)(=[O:28])[C:16]1[CH:27]=[CH:26][C:19]([C:20]([O:22][CH2:23][CH2:24][CH3:25])=[O:21])=[CH:18][CH:17]=1.[OH-].[K+].C1(C)C=CC=CC=1>C(O)CC>[C:20]([O:22][CH2:23][CH2:24][CH3:25])(=[O:21])[C:19]1[CH:26]=[CH:27][C:16]([C:15]([O-:29])=[O:28])=[CH:17][CH:18]=1.[K+:14]

参加物

6

反応物 4

HCID 1140TolueneHCID 14797Potassium HydroxideHCID 1212461,4-Dipropyl 1,4-benzenedicarboxylateHCID 236837531,4-Benzenedicarboxylic acid, 1-methyl ester, potassium salt (1:1)

生成物 1

HCID 23693908HCID 23693908、化合物収率 95%

試薬・触媒・溶媒 1

HCID 10311-Propanol溶媒

実験手順

This compound was prepared by the procedure described for potassium monomethyl terephthalate. Typical reagent levels were as follows: dipropyl terephthalate (97.3 g, 0.39 mole), potassium hydroxide (22.0g, 0.39 mole), 100 ml of toluene and 200 ml of 1-propanol. After workup 92.0 g of product was recovered which represented a 95% yield.

後処理

  1. customThis compound was prepared by the procedure
  2. customAfter workup 92.0 g of product was recovered which

出典と根拠

ORDレコード
ord-2d332b71e2f240c6b6b0b6466f7d809c
出典データセット
uspto-grants-1992_01
特許番号
US05078907

反応ノート

読み込み中…