1-Hexanol → 1,4-Benzenedicarboxylic acid, 1-methyl ester, potassium salt (1:1)

HRID 1089647

反応式

HRID 1089647 の反応式
[C:1]([O:18]CCCCCC)(=[O:17])[C:2]1[CH:16]=[CH:15][C:5]([C:6]([O:8][CH2:9]CCCCC)=[O:7])=[CH:4][CH:3]=1.[OH-].[K+:26].C(O)CCCCC>C1(C)C=CC=CC=1>[C:6]([O:8][CH3:9])(=[O:7])[C:5]1[CH:15]=[CH:16][C:2]([C:1]([O-:18])=[O:17])=[CH:3][CH:4]=1.[K+:26]

参加物

5

反応物 3

HCID 81031-HexanolHCID 14797Potassium HydroxideHCID 519527Dihexyl terephthalate

生成物 1

HCID 236837531,4-Benzenedicarboxylic acid, 1-methyl ester, potassium salt (1:1)

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

Typical reagent levels were as follows: dihexyl terephthalate (33.5 g, 0.10 mole), potassium hydroxide (5.6 g, 0.10 mole), 100 ml of toluene and 20 ml of 1-hexanol. After workup 20.2g (70%) of product was recovered.

後処理

  1. customAfter workup 20.2g (70%) of product was recovered

出典と根拠

ORDレコード
ord-cf7e5e903a6647c694d5ca44036477cf
出典データセット
uspto-grants-1992_01
特許番号
US05078907

関連ノート

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