Myristic Acid → Tetradecanoic acid, cadmium salt (2:1)

HRID 1095205

反応式

HRID 1095205 の反応式
[N+]([O-])([O-])=O.[Cd+2:5].[N+]([O-])([O-])=O.[OH-].[Na+].[C:12]([OH:27])(=[O:26])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].[C:28]([O-:43])(=[O:42])[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41].[Na+]>CO>[C:12]([O-:27])(=[O:26])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].[Cd+2:5].[C:28]([O-:43])(=[O:42])[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH3:41]

参加物

6

反応物 4

HCID 11005Myristic AcidHCID 14798Sodium HydroxideHCID 25154Cadmium Nitrate2 回HCID 23693095Sodium Myristate

生成物 1

HCID 66290Tetradecanoic acid, cadmium salt (2:1)

試薬・触媒・溶媒 1

HCID 887Methanol溶媒2 回

実験手順

Cadmium nitrate (5 mmol) was dissolved in anhydrous methanol (50 mL). A sodium-myristate solution was prepared by dissolving sodium hydroxide (15 mmol) and myristic acid (15 mmol) in anhydrous methanol (500 mL). Then the cadmium-nitrate solution was added dropwise (one drop per second) into the sodium-myristate solution with vigorous stirring. The resulting white precipitate was washed with methanol three times, and then dried at ˜60° C. under vacuum overnight.

後処理

  1. washThe resulting white precipitate was washed with methanol three times
  2. customdried at ˜60° C. under vacuum overnight

出典と根拠

ORDレコード
ord-f36c17c4339b4b88b5e836b296c9a53d
出典データセット
uspto-grants-2012_03
特許番号
US08137457B2

関連ノート

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