HCID 86657328、化合物 → Ethyl (6,7,8,9-tetrahydro-5H-5-benzocycloheptenyl)acetate
反応式
[CH:1]1[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][C:11](=[CH:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])[C:5]=2[CH:4]=[CH:3][CH:2]=1>C(OCC)(=O)C.[Pd]>[CH:1]1[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][CH:11]([CH2:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])[C:5]=2[CH:4]=[CH:3][CH:2]=1参加物
4
実験手順
A solution of ethyl (6,7,8,9-tetrahydro-5-benzocycloheptenylidene)acetate (0.550 g) in ethyl acetate (10 ml) was added with 10% palladium/carbon (0.055 g), and the mixture was stirred for 3 hours under a hydrogen flow. The reaction mixture was filtered through Celite, and then the solvent of the filtrate was concentrated under reduced pressure to obtain the title compound (0.551 g, yield: 99%).
後処理
- filtrationThe reaction mixture was filtered through Celite
- concentrationthe solvent of the filtrate was concentrated under reduced pressure
出典と根拠
- ORDレコード
- ord-39043f1c2ba34e94bc103a80b7c87ffe
- 出典データセット
- uspto-grants-2012_03
- 特許番号
- US08143260B2
反応ノート
読み込み中…