2-Octanol → Propan-2-yl 2-dodecylbenzene-1-sulfonate

HRID 1109090

反応式

HRID 1109090 の反応式
CC(O)CCCCCC.[CH2:10]([C:22]1C=CC=C[C:23]=1S(Cl)(=O)=O)[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]CC.[C:32]1(C)[CH:37]=[CH:36][C:35]([S:38]([O:41][CH:42]([CH3:49])[CH2:43]CCCCC)(=[O:40])=[O:39])=[CH:34][CH:33]=1>>[CH2:19]([C:34]1[CH:33]=[CH:32][CH:37]=[CH:36][C:35]=1[S:38]([O:41][CH:42]([CH3:43])[CH3:49])(=[O:39])=[O:40])[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:22][CH3:23]

参加物

4

反応物 3

HCID 200832-OctanolHCID 3912199HCID 3912199、化合物HCID 204390012-Dodecylbenzene-1-sulfonyl chloride

生成物 1

HCID 23368822Propan-2-yl 2-dodecylbenzene-1-sulfonate収率 83%

実験手順

In the Example of preparation of material 18, 2-octanol was used in place of 2-propanol in the Example of preparation of material 17. In the Example of preparation of material 19, dodecylbenzene sulfonyl chloride was used in place of p-toluene sulfonyl chloride in the Example of preparation of material 17. Other procedures were made in the same way as the Example of preparation of material 17. In the Example of preparation of material 18, 1-methylheptyl p-toluene sulfonate was obtained in the yield of 72% and, in the Example of preparation of material 19, 1-methylethyl dodecylbenzene sulfonate was obtained in the yield of 83%.

出典と根拠

ORDレコード
ord-fcde6d5423e74d30ae06c643be62027b
出典データセット
uspto-grants-1994_06
特許番号
US05319024

関連ノート

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