Thionyl Chloride → 4'-n-Nonyloxybiphenyl-4-carboxylic acid chloride

HRID 1109430ノート

反応式

HRID 1109430 の反応式
[CH2:1]([O:10][C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][C:20]([C:23]([OH:25])=O)=[CH:19][CH:18]=2)=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].S(Cl)([Cl:28])=O>>[CH2:1]([O:10][C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][C:20]([C:23]([Cl:28])=[O:25])=[CH:19][CH:18]=2)=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

参加物

3

反応物 2

HCID 24386Thionyl Chloride2 回HCID 36202634'-(Nonyloxy)[1,1'-biphenyl]-4-carboxylic acid

生成物 1

HCID 120802734'-n-Nonyloxybiphenyl-4-carboxylic acid chloride

実験手順

After 1.2 g of 4'-n-nonyloxybiphenyl-4-carboxylic acid was heated together with an excess amount of thionyl chloride for 6 hours under a reflux condition, unaltered thionyl chloride was distilled off to obtain 1.25 g of 4'-n-nonyloxybiphenyl-4-carboxylic acid chloride.

後処理

  1. distillationwas distilled off

出典と根拠

ORDレコード
ord-b75ec5e9a4644b7d97f746bc7a0b9d13
出典データセット
uspto-grants-1994_06
特許番号
US05320776

反応ノート

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