4,4'-Butylidenebis(3-methyl-6-tert-butylphenol) → 2,2'-Methylenebis(4-methyl-6-tert-butylphenol)

HRID 1109461

反応式

HRID 1109461 の反応式
[CH2:1]([C:15]1[CH:20]=[C:19]([CH2:21]C)[CH:18]=[C:17]([C:23]([CH3:26])([CH3:25])[CH3:24])[C:16]=1[OH:27])[C:2]1[CH:7]=[C:6]([CH2:8]C)[CH:5]=[C:4]([C:10]([CH3:13])([CH3:12])[CH3:11])[C:3]=1[OH:14].C(C1C=C(C)C=C(C2CCCCC2)C=1O)C1C=C(C)C=C(C2CCCCC2)C=1O.C(C1C=C(C)C=C(CCCCCCCCC)C=1O)C1C=C(C)C=C(CCCCCCCCC)C=1O.C(C1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1O)C1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1O.C(C1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1O)(C1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1O)C.C(C1C=C(CC(C)C)C=C(C(C)(C)C)C=1O)(C1C=C(CC(C)C)C=C(C(C)(C)C)C=1O)C.C(C1C=C(CCCCCCCCC)C=C(C(C)C2C=CC=CC=2)C=1O)C1C=C(CCCCCCCCC)C=C(C(C)C2C=CC=CC=2)C=1O.C(C1C=C(CCCCCCCCC)C=C(C(C)C2C=CC=CC=2C)C=1O)C1C=C(CCCCCCCCC)C=C(C(C)C2C=CC=CC=2C)C=1O.C(C1C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=1)C1C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=1.C(C1C=C(C(C)(C)C)C(O)=C(C)C=1)C1C=C(C(C)(C)C)C(O)=C(C)C=1.C(C1C(O)=CC(C)=C(C(C2C=C(C(C)(C)C)C(O)=CC=2C)CCC)C=1)(C)(C)C.C(C1C(O)=C(C=C(C)C=1)CC1C=C(C)C=C(CC2C=C(C)C=C(C(C)(C)C)C=2O)C=1O)(C)(C)C>>[CH2:1]([C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[C:4]([C:10]([CH3:13])([CH3:12])[CH3:11])[C:3]=1[OH:14])[C:15]1[CH:20]=[C:19]([CH3:21])[CH:18]=[C:17]([C:23]([CH3:26])([CH3:25])[CH3:24])[C:16]=1[OH:27]

参加物

13

反応物 12

HCID 68154,4'-Butylidenebis(3-methyl-6-tert-butylphenol)HCID 69282,2'-Methylenebis(4-ethyl-6-tert-butylphenol)HCID 83724,4'-Methylenebis(2,6-di-tert-butylphenol)HCID 245822,2'-Methylenebis(4-methyl-6-nonylphenol)HCID 666622,6-Bis(4-methyl-6-tert-butyl-salicyl)-4-methylphenolHCID 667826,6'-Di-tert-butyl-4,4'-methylenedi-o-cresolHCID 776812,2'-Methylenebis(6-cyclohexyl-p-cresol)HCID 843912,2'-Methylenebis(4,6-di-tert-butylphenol)HCID 1188992,2'-Ethylidenebis(4,6-di-tert-butylphenol)HCID 142522202,2'-Ethylidenebis (6-tert-butyl-4-isobutylphenol)HCID 142748222,2'-Methylenebis [6-(alpha-methylbenzyl)-4-nonylphenol]HCID 537288292,2'-Methylenebis [6-(2, alpha-dimethylbenzyl)-4-nonyl-phenol]

生成物 1

HCID 83982,2'-Methylenebis(4-methyl-6-tert-butylphenol)

実験手順

2,2'-methylenebis (6-tert-butyl-4-ethylphenol); 2,2'-methylenebis [4-methyl-6-(α-methylcyclohexyl) -phenol]; 2,2'-methylenebis (4-methyl-6-cyclohexylphenol); 2,2'-methylenebis (6-nonyl-4-methylphenol); 2,2'-methylenebis (4,6-di-tert-butylphenol); 2,2'-ethylidenebis (4,6-di-tert-butylphenol); 2,2'-ethylidenebis (6-tert-butyl-4-isobutylphenol); 2,2'-methylenebis [6-(α-methylbenzyl)-4-nonylphenol]; 2,2'-methylenebis [6- (2, α-dimethylbenzyl)-4-nonyl-phenol]; 4,4'-methylenebis (2,6-di-tert-butylphenol); 4,4'-methylenebis (6-tert-butyl-2-methylphenol); 1,1-bis (5-tert-butyl-4-hydroxy-2-methylphenyl) butane; 2,6-di (3-tert-butyl-5-methyl-2-hydroxybenzyl) -4-methylphenol; 1,1,3-tris (5-tert-butyl-4-hydroxy-2-methylphenyl)-3-n-dodecylmercapobutane; ethylene glycol bis [3,3-bis (3'-tert-butyl-4'-hydroxylphenyl) butyrate]; di(3-tert-butyl-4-hydroxy-5-methylphenyl) dicyclopentadiene; di[2-(3'-tert-butyl-2'-hydroxy-5'-methylbenzyl)-6-tertbutyl -4-methyl pheny] terephthalate.

出典と根拠

ORDレコード
ord-d0882fe2d473456a80da89c0291ede2a
出典データセット
uspto-grants-1994_06
特許番号
US05320765

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