Methyl iodide → HCID 138962835、化合物
反応式
[NH2:1][C:2](=[S:12])[NH:3][C:4](=[O:11])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[CH3:13]I>CC(C)=O>[C:4]([NH:3][C:2]([S:12][CH3:13])=[NH:1])(=[O:11])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1参加物
4
実験手順
To an 18.0 g (0.1 mole) amount of N-(aminothioxomethyl)benzamide in 300 ml of acetone was added 15.0 ml of methyl iodide (34.2 g, 0.24 mole). The mixture was heated as reflux and after about 5 minutes a solid precipitate formed. Refluxing was continued for 2 hours, then the hot reaction mixture was filtered to collect the precipitate. The precipitate was washed with two 50 ml portions of acetone, then air dried to give 28.9 g of the product as a white solid, mp 189°-190° C. (dec.).
後処理
- temperatureThe mixture was heated
- temperatureas reflux and after about 5 minutes a solid precipitate
- customformed
- temperatureRefluxing
- filtrationthe hot reaction mixture was filtered
- customto collect the precipitate
- washThe precipitate was washed with two 50 ml portions of acetone
- customair dried
出典と根拠
- ORDレコード
- ord-0613752098c74cfdbdb44bbf872a653c
- 出典データセット
- uspto-grants-1990_12
- 特許番号
- US04977189
反応ノート
読み込み中…