Vinyl Acetate → 1,1-Ethanediol, 1,1-diacetate

HRID 1111242

反応式

HRID 1111242 の反応式
[C:1]([O:4][CH:5]=[CH2:6])(=[O:3])[CH3:2]>[Pd](Cl)Cl.C(O)(=O)C>[C:1]([O:4][CH:5]([O:4][C:1](=[O:3])[CH3:2])[CH3:6])(=[O:3])[CH3:2]

参加物

4

反応物 1

HCID 7904Vinyl Acetate

生成物 1

HCID 2225361,1-Ethanediol, 1,1-diacetate収率 2,504.6%

試薬・触媒・溶媒 2

HCID 24290Palladium Chloride触媒HCID 176Acetic Acid溶媒

実験手順

The procedure of Example 9 was repeated except that 0.451 g of palladium chloride was used in place of palladium supported on activated carbon and the reaction was effected for 3 hours. GC analysis showed that 1.51 g of vinyl acetate and 32.1 g of ethylidene diacetate were formed with considerable amount of acetic acid.

出典と根拠

ORDレコード
ord-a9b5c18e35584c908a6278b712e5c952
出典データセット
uspto-grants-1990_12
特許番号
US04978778

関連ノート

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