Sodium Cyanide → Fenvalerate

HRID 1112605

反応式

HRID 1112605 の反応式
[O:1]([C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][CH:15]=1)[CH:11]=[O:12])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:16][C:17]1[CH:22]=[CH:21][C:20]([CH:23]([CH:27]([CH3:29])[CH3:28])[C:24](Cl)=[O:25])=[CH:19][CH:18]=1.[C-:30]#[N:31].[Na+]>O.CCCCCCC>[Cl:16][C:17]1[CH:22]=[CH:21][C:20]([CH:23]([CH:27]([CH3:29])[CH3:28])[C:24]([O:12][CH:11]([C:30]#[N:31])[C:10]2[CH:13]=[CH:14][CH:15]=[C:8]([O:1][C:2]3[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=3)[CH:9]=2)=[O:25])=[CH:19][CH:18]=1

参加物

6

反応物 3

HCID 8929Sodium Cyanide3 回HCID 382843-PhenoxybenzaldehydeHCID 41780012-(4-Chlorophenyl)-3-methylbutanoyl chloride

生成物 1

HCID 3347Fenvalerate

試薬・触媒・溶媒 2

HCID 962Water溶媒2 回HCID 8900Heptane溶媒

実験手順

A 500 ml round-bottomed flask equipped with a paddle stirrer was charged with 100 mmol of 3-phenoxybenzaldehyde, 100 mmol of 2-(4-chlorophenyl)-3-methylbutanoyl chloride, 120 mmol of sodium cyanide, 10 ml of water, and 200 ml of n-heptane. The molar ratio of water to sodium cyanide was 4.64, all NaCN being dissolved. The mixture thus formed was stirred and analysed. Table VI presents the yields and purities of the desired ester after the reaction time indicated.

後処理

  1. customA 500 ml round-bottomed flask equipped with a paddle stirrer
  2. customThe mixture thus formed
  3. customyields

出典と根拠

ORDレコード
ord-dced4548778d4b5fbc68b4a165a71eaa
出典データセット
uspto-grants-1978_10
特許番号
US04123451

関連ノート

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