2-Heptanone → 2-Heptanone

HRID 1155207

反応式

HRID 1155207 の反応式
[CH3:1][C:2](=[O:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]>C1(C)C=CC=CC=1>[CH3:1][CH:2]([OH:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH3:1][C:2](=[O:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

参加物

4

反応物 1

HCID 80512-Heptanone

生成物 2

HCID 80512-HeptanoneHCID 109762-Heptanol

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒3 回

実験手順

Operating under the conditions of Example 1, 1 millimol of 2-heptanone in toluene (1 ml of a 1M soln.) is reacted with 0.375 millimol of Ca[AlH2 (OCH2CH2OCH3)2 ]2 in toluene (1.78 ml of a 0.21M soln.) during 30 mins. at room temperature. After treating the reaction mixture according to the procedure of Example 1, the resultant toluene solution is gaschromatographically analyzed. The yield of 2-heptanol, the result of the reduction of 2-heptanone, is quantitative.

後処理

  1. customat room temperature
  2. additionAfter treating the reaction mixture

出典と根拠

ORDレコード
ord-5c29ef634ca14ab7a590912e3ad00693
出典データセット
uspto-grants-1981_11
特許番号
US04299986

関連ノート

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