2-Chlorooctane → HCID 12790089、化合物

HRID 1155303

反応式

HRID 1155303 の反応式
[Mg].Cl[CH:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:4].[CH3:11][CH:12]([Mg]Cl)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:21]([Sn:25](Cl)(Cl)Cl)[CH2:22][CH2:23][CH3:24]>C1(C)C(C)=CC=CC=1.O1CCCC1>[CH2:21]([Sn:25]([CH:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:4])([CH:12]([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[CH3:11])[CH:3]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])[CH3:4])[CH2:22][CH2:23][CH3:24]

参加物

7

反応物 4

HCID 123472-ChlorooctaneHCID 14236Butyltin trichlorideHCID 5462224MagnesiumHCID 178443929HCID 178443929、化合物

生成物 1

HCID 12790089HCID 12790089、化合物

試薬・触媒・溶媒 2

HCID 7237O-Xylene溶媒HCID 8028Tetrahydrofuran溶媒

実験手順

A 1-liter four-necked flask equipped with a thermometer, a condenser, a stirrer and a dropping funnel was charged with 19.4 g (0.8 mole) of magnesium, 118.9 g (0.8 mole) of 2-chlorooctane and 200 g of tetrahydrofuran, and they were reacted in a stream of nitrogen. To the resulting 2-octyl magnesium chloride solution was added dropwise a solution of 67.7 g (0.24 mole) of mono-n-butyltin trichloride in 200 ml of xylene with stirring at room temperature over the course of 30 minutes. The reaction mixture was reacted for 3 hours at the refluxing temperature, and then subjected to hydrolysis to obtain 120 g of n-butyl tri-2-octyltin having a purity of 98.7%.

後処理

  1. customA 1-liter four-necked flask equipped with a thermometer, a condenser, a stirrer and a dropping funnel
  2. customwere reacted in a stream of nitrogen
  3. customThe reaction mixture was reacted for 3 hours at the refluxing temperature
  4. customsubjected to hydrolysis

出典と根拠

ORDレコード
ord-4cdc75f395404d33805bdc9bb50f4a64
出典データセット
uspto-grants-1981_11
特許番号
US04301173

関連ノート

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