2-Propenal, 3-(2-methoxyphenyl)- → HCID 70554850、化合物

HRID 1155768ノート

反応式

HRID 1155768 の反応式
[CH3:1][O:2][C:3]1[CH:12]=[CH:11][CH:10]=[CH:9][C:4]=1[CH:5]=[CH:6][CH:7]=O.[CH3:13][N:14]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[NH2:15]>Cl.C(O)C>[CH3:13][N:14]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)[N:15]=[CH:7][CH:6]=[CH:5][C:4]1[CH:9]=[CH:10][CH:11]=[CH:12][C:3]=1[O:2][CH3:1]

参加物

5

反応物 2

HCID 151732-Propenal, 3-(2-methoxyphenyl)-HCID 36299N-methyl-N-phenyl-hydrazine

生成物 1

HCID 70554850HCID 70554850、化合物

試薬・触媒・溶媒 2

HCID 313Hydrochloric Acid触媒HCID 702Ethanol溶媒

実験手順

3.2 g of 2-methoxycinnamaldehyde and 2.4 g of 1-methyl-1-phenylhydrazine were added to 50 ml of ethanol. To the mixture, two or three drops of 1 N hydrochloric acid were added. The mixture was heated and refluxed for about one hour. The reaction mixture was cooled and the crystals then separated, which were then collected on a suctional funnel. The thus obtained crude 2-methoxycinnamaldehyde 1-methyl-1-phenylhydrazone was recrystallized from ethanol. The yield was 2.6 g (49.1%) of light yellow scalelike crystals which melt at 100.5°-101.5° C.

後処理

  1. temperatureThe mixture was heated
  2. temperaturerefluxed for about one hour
  3. temperatureThe reaction mixture was cooled
  4. customthe crystals then separated
  5. customwhich were then collected on a suctional funnel

出典と根拠

ORDレコード
ord-86270fe639d9490088f577b21007197e
出典データセット
uspto-grants-1982_06
特許番号
US04332948

反応ノート

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