Triethylamine → 1-(p-CHLOROPHENYLSULFONYL)VINYL PHENYL SULFIDE

HRID 1156387ノート

反応式

HRID 1156387 の反応式
[C:1]1([S:7][CH:8]([S:11]([C:14]2[CH:19]=[CH:18][C:17]([Cl:20])=[CH:16][CH:15]=2)(=[O:13])=[O:12])[CH2:9]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(N(CC)CC)C>O1CCCC1>[C:1]1([S:7][C:8]([S:11]([C:14]2[CH:15]=[CH:16][C:17]([Cl:20])=[CH:18][CH:19]=2)(=[O:13])=[O:12])=[CH2:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

参加物

4

反応物 2

HCID 8471TriethylamineHCID 130447952-CHLORO-1-(p-CHLOROPHENYLSULFONYL)ETHYL PHENYL SULFIDE

生成物 1

HCID 205359981-(p-CHLOROPHENYLSULFONYL)VINYL PHENYL SULFIDE

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

To a solution of 30 g (86.5 mmoles) of 2-chloro-1-(p-chlorophenylsulfonyl)ethyl phenyl sulfide in 100 ml of tetrahydrofuran was added 12.2 ml (8.88 g, 87.8 mmoles) of triethylamine. After two hours the reaction mixture was filtered to remove triethylamine hydrochloride. The filtrate was evaporated down under reduced pressure, first at 15 mm and finally at 0.01 mm (25° C.), to give a light yellow oil.

後処理

  1. filtrationAfter two hours the reaction mixture was filtered
  2. customto remove triethylamine hydrochloride
  3. customThe filtrate was evaporated down under reduced pressure, first at 15 mm and finally at 0.01 mm (25° C.)
  4. customto give a light yellow oil

出典と根拠

ORDレコード
ord-f6709858b81d4de18b23bf71e816d299
出典データセット
uspto-grants-1982_06
特許番号
US04335142

反応ノート

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