Triethylamine → p-BROMOPHENYL 1-(PHENYLSULFONYL)VINYL SULFIDE

HRID 1156388ノート

反応式

HRID 1156388 の反応式
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH:9]([S:12]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)(=[O:14])=[O:13])[CH2:10]Cl)=[CH:4][CH:3]=1.C(N(CC)CC)C>O1CCCC1.C(OCC)C>[C:15]1([S:12]([C:9]([S:8][C:5]2[CH:4]=[CH:3][C:2]([Br:1])=[CH:7][CH:6]=2)=[CH2:10])(=[O:14])=[O:13])[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

参加物

5

反応物 2

HCID 8471TriethylamineHCID 130447982-CHLORO-1-(PHENYLSULFONYL)ETHYL p-BROMOPHENYL SULFIDE

生成物 1

HCID 13044810p-BROMOPHENYL 1-(PHENYLSULFONYL)VINYL SULFIDE

試薬・触媒・溶媒 2

HCID 3283Diethyl Ether溶媒HCID 8028Tetrahydrofuran溶媒

実験手順

A solution of 10.2 g (26.1 mmoles) of 2-chloro-1-(phenylsulfonyl)ethyl p-bromophenyl sulfide in 50 ml of tetrahydrofuran was diluted with 50 ml of diethyl ether and treated with 3.63 ml (2.65 g, 26.2 mmoles) of triethylamine. After 20 minutes the triethylamine hydrochloride was removed by filtration. The filtrate was freed of solvent by evaporation under reduced pressure to leave a viscous, pale yellow oil of n20 1.6338.

後処理

  1. customAfter 20 minutes the triethylamine hydrochloride was removed by filtration
  2. customThe filtrate was freed of solvent by evaporation under reduced pressure
  3. customto leave a viscous, pale yellow oil of n20 1.6338

出典と根拠

ORDレコード
ord-ed20170bc6fc4bc284c0ff987a8d92c0
出典データセット
uspto-grants-1982_06
特許番号
US04335142

反応ノート

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