反応式
C(N([CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])CCCCCCCC)CCCCCCC.C(C(CC[CH2:49][CH3:50])CN(CC(CC)CCCC)CC(CC)CCCC)C.C(N(C1CCCCC1)C1CCCCC1)C.C(N(C(C)C)C(C)C)C.CN1C(C)(C)CCCC1(C)C.[C:86]([O-:89])(=[O:88])C.[Li+].C([O-])(=O)C.C[N+](C)(C)CC1C=CC=CC=1>C(N(CC)CC)C>[C:86]([O:89][CH2:49][CH3:50])(=[O:88])[CH:25]=[CH:24][C:23]1[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=1参加物
9
反応物 7
生成物 1
試薬・触媒・溶媒 1
実験手順
The procedure described in Example 1 is repeated, except that 0.03125 mol of one of the bases tri-n-octylamine, tris-(2-ethylhexyl)-amine, ethyl-dicyclohexylamine, triethylamine, ethyl-diisopropylamine, N-methyl-2,2,6,6-tetramethylpiperidine, lithium acetate and trimethyl-benzylammonium acetate is used in place of 0.03125 mol of tri-n-butylamine. After working up as described in Example 1, ethyl cinnamate is obtained in comparably good yields.
出典と根拠
- ORDレコード
- ord-e511e4f9f090421ca5ee66ff077b40fb
- 出典データセット
- uspto-grants-1982_06
- 特許番号
- US04335054
関連ノート
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