化工社化工社 化学情報印刷レポート · 研究参考用
1-Phenethylamine → 1-Phenethylamine, (+)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Phenethylamine | HCID 7408 | — |
| 反応物 | (R)-(-)-2-propyloctanoic acid | HCID 208925 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 1-Phenethylamine, (+)- | HCID 643189 | 88.2% |
反応手順
Using the crystal comprising (2R)-2-propyloctanoic acid and R)-(+)-1-phenylethylamine (6.8 g) produced in the second recrystallization and acetonitrile (102 mL), the same operation as in the second recrystallization was made to give the crystal comprising (2R)-2-propyloctanoic acid and (R)-(+)-1-phenylethylamine (6.0 g, 98.9% e.e.; yield 88%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07820715B2 |
| 出典データセット | uspto-grants-2010_10 |
| ORD ID | ord-54191d2ebb5b469a828f5070eff5df6b |
| 出典メモ | uspto-grants-2010_10 |