Thionyl Chloride → 2-[(Phenylmethyl)thio]benzoyl chloride
反応式
[C:1]1([CH2:7][S:8][C:9]2[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=2[C:11](O)=[O:12])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:20])=O>C1C=CC=CC=1>[C:1]1([CH2:7][S:8][C:9]2[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=2[C:11]([Cl:20])=[O:12])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
4
実験手順
A suspension of 100 g of 2-[(phenylmethyl)thio]benzoic acid and 97.6 g of thionyl chloride in 800 ml of benzene was refluxed for about three hours then evaporated to dryness under vacuum. The residue was triturated with hexane to yield 101.2 g of 2-[(phenylmethyl)thio]benzoyl chloride, m.p. 113° to 116° C.
後処理
- temperaturewas refluxed for about three hours
- customthen evaporated to dryness under vacuum
- customThe residue was triturated with hexane
出典と根拠
- ORDレコード
- ord-6fc63a9e303d43e2bf6ca3d5569fc421
- 出典データセット
- uspto-grants-1990_03
- 特許番号
- US04906282
反応ノート
読み込み中…