Trimethyl Phosphate → HCID 178502937、化合物

HRID 1168025

反応式

HRID 1168025 の反応式
[I-].[C:2]1([S+:8]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[P:21](OC)([O:25][CH3:26])([O:23][CH3:24])=[O:22]>>[CH3:24][O:23][PH:21](=[O:22])[O:25][CH3:26].[C:15]1([S+:8]([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=1

参加物

3

反応物 2

HCID 10541Trimethyl PhosphateHCID 21881071Triphenylsulfonium iodide

生成物 1

HCID 178502937HCID 178502937、化合物収率 75%

反応条件

温度
130 °C

実験手順

A mixture of triphenylsulfonium iodide (390 mg; 1 mmol) and trimethyl phosphate (1 g) was stirred at 130° C. for 3 hours. Subsequently, the homogenous solution was cooled, and the thus-obtained solid matter was washed with IPA, to thereby yield 280 mg of the target compound as white crystals (yield: 72.2%). The anion content of the resultant compound was determined by ion chromatography. The iodide anion content was determined to be not greater than 50 ppm.

後処理

  1. temperatureSubsequently, the homogenous solution was cooled
  2. washthe thus-obtained solid matter was washed with IPA

出典と根拠

ORDレコード
ord-3e2c4f206b8748ee8d145081cbc59692
出典データセット
uspto-grants-2003_09
特許番号
US06620957B1

関連ノート

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