Benzoyl chloride → 4-Methoxybenzophenone

HRID 1180324

反応式

HRID 1180324 の反応式
[C:1]1([O:7][CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:9](Cl)(=[O:16])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.B12B3B4B1C234>C1C=CC=CC=1>[CH3:8][O:7][C:1]1[CH:6]=[CH:5][C:4]([C:9](=[O:16])[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:3][CH:2]=1

参加物

5

反応物 3

HCID 7412Benzoyl chlorideHCID 7519AnisoleHCID 123279Boron carbide

生成物 1

HCID 691464-Methoxybenzophenone収率 48.2%

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

A mixture of 5.4 gm (0.05 moles) of anisole and 7.0 gm (0.05) moles of benzoyl chloride and 0.5 gm of boron carbide was placed in 50 ml of benzene. This mixture was allowed to react as described in Example 3. A yield of 48.2% of p-methoxy benzophenone was obtained, and 0.5 gm of the boron carbide catalysts was recovered.

後処理

  1. customto react

出典と根拠

ORDレコード
ord-1185fc3e6a64469d9b8dbfeb70c90873
出典データセット
uspto-grants-2007_10
特許番号
US07279604B2

関連ノート

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