Water → N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

HRID 1182267ノート

反応式

HRID 1182267 の反応式
[C:1]1([CH3:13])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9](Cl)(=[O:11])=[O:10].[CH3:14][C:15](=[N:17][OH:18])[CH3:16].O>N1C=CC=CC=1>[CH3:13][C:1]1[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9]([O:18][N:17]=[C:15]([CH3:16])[CH3:14])(=[O:11])=[O:10]

参加物

5

反応物 3

HCID 962WaterHCID 130462-Mesitylenesulfonyl chlorideHCID 67180Acetone, oxime

生成物 1

HCID 279802N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

To a solution of mesitylenesulfonyl chloride (2.0 g, 9.05 mmol) in pyridine (30 mL) was added acetone oxime (0.67 g, 9.05 mmol), and the solution was stirred under N2 for 16 hours. It was poured into 500 ml of water and stirred for 1 hour. The precipitate was filtered and dried Acetone O-(2,4,6-trimethylphenylsulfonyl)oxime was obtained as white powder (57.6%) yield.

後処理

  1. stirringstirred for 1 hour
  2. filtrationThe precipitate was filtered

出典と根拠

ORDレコード
ord-9d90ae9d63cc44f2baa2f64a3f172a1c
出典データセット
uspto-grants-2007_10
特許番号
US07288538B2

反応ノート

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