m-Chloroperbenzoic acid → HCID 86679095、化合物

HRID 1183476

反応式

HRID 1183476 の反応式
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[N:3]=1.ClC1C=CC=C(C(OO)=[O:23])C=1>C(Cl)Cl>[C:9]1([S:8]([C:4]2[CH:5]=[CH:6][CH:7]=[C:2]([Br:1])[N:3]=2)=[O:23])[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

参加物

4

反応物 2

HCID 70297m-Chloroperbenzoic acidHCID 8245912-Bromo-6-phenylsulfanylpyridine

生成物 1

HCID 86679095HCID 86679095、化合物

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

2-Bromo-6-phenylsulfanyl-pyridine (0.5323 g, 2 mmol) was dissolved in CH2Cl2 (20 mL) and m-chloroperbenzoic acid (0.345 g, 2 mmol) was added. The reaction was stirred at room temperature overnight then submitted to aqueous workup and purification on silica gel to give the title compound.

後処理

  1. customthen submitted to aqueous workup and purification on silica gel

出典と根拠

ORDレコード
ord-26914c45d55841a4a736b549738cd277
出典データセット
uspto-grants-2014_03
特許番号
US08664220B2

関連ノート

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