Sodium Hydroxide → Undeca-2,4,8-trienoic acid
反応式
[CH:1](=[O:12])[CH:2]=[CH:3][CH:4]=[CH:5][CH2:6][CH2:7][CH:8]=[CH:9][CH2:10][CH3:11].[OH-:13].[Na+]>O.[Ag-]=O>[C:1]([OH:13])(=[O:12])[CH:2]=[CH:3][CH:4]=[CH:5][CH2:6][CH2:7][CH:8]=[CH:9][CH2:10][CH3:11]参加物
5
反応条件
- 温度
- 20 °C
実験手順
For example, the 2,4,8-undecatrienal is added to a suspension of silver (I) oxide (1.1 eq) in water. The mixture is stirred at 20° C. and 50% sodium hydroxide solution (equal weight to the aldehyde), is added over 30 minutes allowing the batch to exotherm to 60° C. The solution is filtered through celite, and the aqueous filtrate acidified to pH 1 with hydrochloric acid solution, to give 2,4,8-undecatrienoic acid.
後処理
- customto exotherm to 60° C
- filtrationThe solution is filtered through celite
出典と根拠
- ORDレコード
- ord-749372d48f064457a6708bf563870855
- 出典データセット
- uspto-grants-2006_08
- 特許番号
- US07098350B2
反応ノート
読み込み中…