Methyldichlorosilane → Silane, dichloro-5-hexen-1-ylmethyl-

HRID 1197898ノート

反応式

HRID 1197898 の反応式
[CH2:1]([Si:7]([CH3:10])(C)[Cl:8])[CH2:2][CH2:3][CH2:4][CH:5]=[CH2:6].C=CCCC=C.C[SiH](Cl)[Cl:19]>[Pt]>[CH2:1]([Si:7]([CH3:10])([Cl:8])[Cl:19])[CH2:2][CH2:3][CH2:4][CH:5]=[CH2:6]

参加物

5

反応物 3

HCID 6376MethyldichlorosilaneHCID 115981,5-HexadieneHCID 118299765-Hexenyldimethylchlorosilane

生成物 1

HCID 11063373Silane, dichloro-5-hexen-1-ylmethyl-収率 68%

試薬・触媒・溶媒 1

HCID 23939Platinum触媒

実験手順

Procedure is similar to the one described above for 5-hexenyldimethylchlorosilane. 8.4 g (100 mmole) of 1,5-Hexadiene was refluxed with platinum catalyst (100ppm). To the mixture 5.7 g (50 mmole) of methyldichlorosilane was added dropwise over 30 min. period. The completion of the reaction was monitored by infrared spectroscopy. The product distilling at 65° C./0.22 mm was obtained in 68% yield.

後処理

  1. distillationThe product distilling at 65° C./0.22 mm
  2. customwas obtained in 68% yield

出典と根拠

ORDレコード
ord-29bfa71d9dec400bb8337b4921eda113
出典データセット
uspto-grants-1994_01
特許番号
US05278244

反応ノート

読み込み中…