Anisole → HCID 178503584、化合物
反応式
[CH3:1][S:2][C:3]1[N:4]=[C:5]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=[C:6]2[N:7]=1.[C:13]1(OC)C=CC=CC=1.[F:21][C:22]([F:29])([F:28])[S:23]([O:26]C)(=[O:25])=[O:24]>C(OCC)(=O)C>[F:21][C:22]([F:29])([F:28])[S:23]([O-:26])(=[O:25])=[O:24].[CH3:13][N:7]1[C:6]2=[CH:8][CH:9]=[CH:10][CH:11]=[CH:12][C:5]2=[NH+:4][CH:3]1[S:2][CH3:1]参加物
5
実験手順
First, 25 g of 2-methylthiocycloheptimidazole was added to 100 ml of anisole, and stirred under ice cooling. Then, 28 g of methyl trifluoromethanesulfonate was added dropwise and stirred under ice cooling. The mixture was further stirred at room temperature for 2 hours and 30 minutes, 200 ml of ethyl acetate was added thereto, and deposited crystals were filtered and dried.
後処理
- stirringstirred under ice cooling
- stirringThe mixture was further stirred at room temperature for 2 hours and 30 minutes
- filtrationwere filtered
- customdried
出典と根拠
- ORDレコード
- ord-4fa6b36bb2a74e66b0fcc2d474e62379
- 出典データセット
- uspto-grants-1990_02
- 特許番号
- US04900648
反応ノート
読み込み中…