Anisole → 2-Chloro-3-methylcycloheptimidazolium trifluoromethanesulfonate

HRID 1199344ノート

反応式

HRID 1199344 の反応式
[Cl:1][C:2]1[N:3]=[C:4]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=[C:5]2[N:6]=1.[C:12]1(OC)C=CC=CC=1.[F:20][C:21]([F:28])([F:27])[S:22]([O:25]C)(=[O:24])=[O:23]>C(OCC)(=O)C>[F:20][C:21]([F:28])([F:27])[S:22]([O-:25])(=[O:24])=[O:23].[Cl:1][CH:2]1[NH+:3]=[C:4]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=[C:5]2[N:6]1[CH3:12]

参加物

5

反応物 3

HCID 7519AnisoleHCID 9526Methyl triflateHCID 200643702-Chlorocycloheptimidazole

生成物 1

HCID 1784798762-Chloro-3-methylcycloheptimidazolium trifluoromethanesulfonate

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒

実験手順

2-Chlorocycloheptimidazole (0.78 g) was added to 4 ml of anisole, 0.93 g of methyl trifluoromethanesulfonate was added dropwise thereto, and the mixture was stirred at room temperature for 40 minutes. Then, 50 ml of ethyl acetate was added to the reaction solution, and deposited crystals were collected by filtration and dried.

後処理

  1. additionwas added dropwise
  2. filtrationwere collected by filtration
  3. customdried

出典と根拠

ORDレコード
ord-a28b13fc1c03480d8c0284a09d7a5d6a
出典データセット
uspto-grants-1990_02
特許番号
US04900648

反応ノート

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