p-Toluenesulfonic acid → HCID 20072149、化合物

HRID 1199827

反応式

HRID 1199827 の反応式
[Br:1][CH:2]([CH2:6][C:7]([OH:9])=[O:8])[C:3]([OH:5])=[O:4].[CH2:10](O)[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22].[C:24]1([CH3:34])[CH:29]=[CH:28][C:27](S(O)(=O)=O)=[CH:26][CH:25]=1>C1(C)C=CC=CC=1>[Br:1][CH:2]([CH2:6][C:7]([O:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:24][CH3:34])=[O:8])[C:3]([O:5][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])=[O:4]

参加物

5

反応物 3

HCID 6101p-Toluenesulfonic acidHCID 82071-TridecanolHCID 73557Bromosuccinic acid

生成物 1

HCID 20072149HCID 20072149、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A mixture of 19.7 g. (0.1 mole) of bromosuccinic acid, 40.1 g. (0.2 mole) of tridecanol, 0.25 g. of p-toluenesulfonic acid and 200 ml. of toluene is refluxed for 7 hours, using a Dean-Stark trap. There is collected 3.6 ml. of H2O in the trap which is exactly the calculated amount for this reaction when completed.

後処理

  1. additionA mixture of 19.7 g
  2. customThere is collected 3.6 ml
  3. customfor this reaction when

出典と根拠

ORDレコード
ord-467e94572fd34f74b19f18af15a52433
出典データセット
uspto-grants-1990_02
特許番号
US04902804

関連ノート

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