proline dl-form → 9-Chloro-6-[2-(2-chlorophenyl)prop-1-enyl]-3-methyl-1,2,4,5-tetrahydroazepino[4,5-b]indole

反応式

[Br:17][CH:18]=[C:19]([CH3:20])[c:21]1[c:22]([Cl:27])[cH:23][cH:24][cH:25][cH:26]1.[Cl:1][c:2]1[cH:3][c:4]2[c:5]3[c:6]([nH:7][c:8]2[cH:9][cH:10]1)[CH2:11][CH2:12][N:13]([CH3:16])[CH2:14][CH2:15]3.[Cu:41][I:42].[O:36]=[CH:37][N:38]([CH3:39])[CH3:40].[OH:28][C:29]([CH:30]1[NH:31][CH2:32][CH2:33][CH2:34]1)=[O:35]>>[Cl:1][c:2]1[cH:3][c:4]2[c:5]3[c:6]([n:7]([CH:18]=[C:19]([CH3:20])[c:21]4[c:22]([Cl:27])[cH:23][cH:24][cH:25][cH:26]4)[c:8]2[cH:9][cH:10]1)[CH2:11][CH2:12][N:13]([CH3:16])[CH2:14][CH2:15]3