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Isopropanol → n-(2-Hydroxyethyl)ammonium methyl sulfate

HRID 1242851
ノート
印刷プレビュー

反応式

HRID 1242851 の反応式
[N:1](CCO)(CCO)[CH2:2][CH2:3][OH:4].C(O)(C)C.[S:15]([O:20]C)([O:18][CH3:19])(=[O:17])=[O:16]>C(O)CC>[CH3:19][O:18][S:15]([O-:20])(=[O:17])=[O:16].[OH:4][CH2:3][CH2:2][NH3+:1]
参加物実験手順後処理出典と根拠反応ノート

参加物

5

反応物 3

HCID 3776IsopropanolHCID 6497Dimethyl SulfateHCID 7618Triethanolamine

生成物 1

HCID 22035489n-(2-Hydroxyethyl)ammonium methyl sulfate

試薬・触媒・溶媒 1

HCID 10311-Propanol溶媒

実験手順

Triethanol amine (149 g) and 547 g of hydrogenated tallow fatty acid were used and subjected to an esterification reaction at 200° C. under nitrogen atmosphere for 10 hours, and to this was added 139 g of isopropanol, and this was subjected to a quaternizing reaction at 60° C. by using 126 g of dimethyl sulfate to obtain a propanol solution of N-methyl-N,N-bis (hydrogenated tallow alkanoyl oxyethyl)-N-(2-hydroxyethyl)ammonium methyl sulfate. It was found through NMR measurements that this solution had a long-chain alkyl quaternary ammonium salt content of 12%, a di-long-chain alkyl quaternary ammonium salt content of 35% and mono-long-chain alkyl quaternary ammonium salt content of 15%. The resulting isopropanol solution was taken in a manner so as to set the total amount of quaternary ammonium salt to 5 g, and this was mixed with 2 g of ethyleneoxide 12 mole adduct (HLB=14.0) of hydrogenated tallow fatty acid methyl ester, in the same manner as Example 1 to prepare 100 g of softener composition.

後処理

  1. customsubjected to an esterification reaction at 200° C. under nitrogen atmosphere for 10 hours
  2. customthis was subjected to a quaternizing reaction at 60° C.

出典と根拠

ORDレコード
ord-15eb4628b8f6457aa28907422a17be70
出典データセット
uspto-grants-2006_10
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07115779B2

反応ノート

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