2-Iodophenol → 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
反応式
I[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[OH:8].C1([B:15]2[O:23][C:20]([CH3:22])([CH3:21])[C:17]([CH3:19])([CH3:18])[O:16]2)C=CC=CC=1>>[CH3:18][C:17]1([CH3:19])[C:20]([CH3:22])([CH3:21])[O:23][B:15]([C:7]2[CH:2]=[C:3]([OH:8])[CH:4]=[CH:5][CH:6]=2)[O:16]1参加物
3
実験手順
The above reaction procedure used for 2-iodophenol was followed. The reaction was faster, being complete before the first sample for gc analysis was withdrawn after 1 h 50 min reaction time. The amount of phenylboronic acid pinacol ester was higher than in the 2-iodophenol reaction (around 7%).
後処理
- customThe above reaction procedure
- customwas withdrawn after 1 h 50 min
- customreaction time
出典と根拠
- ORDレコード
- ord-23004de992854d06895bd83361499298
- 出典データセット
- uspto-grants-2006_10
- 特許番号
- US07122694B2
反応ノート
読み込み中…