Potassium Carbonate → Bis(di-p-tolylamino)benzo[a]perylene

HRID 1245252ノート

反応式

HRID 1245252 の反応式
[C:1]1([CH3:15])[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.C(=O)([O-])[O-].[K+].[K+].Br[C:23]1[CH:24]=[C:25]2[C:42]3[C:39]([C:40]=1Br)=[CH:38][CH:37]=[CH:36][C:35]=3[C:34]1[C:43]3[C:30]([CH:31]=[C:32]4[CH:47]=[CH:46][CH:45]=[CH:44][C:33]4=1)=[CH:29][CH:28]=[CH:27][C:26]2=3>O.[Cu]>[C:11]1([CH3:14])[CH:12]=[CH:13][C:8]([N:7]([C:23]2[CH:24]=[C:25]3[C:42]4[C:39]([C:40]=2[N:7]([C:8]2[CH:9]=[CH:10][C:11]([CH3:14])=[CH:12][CH:13]=2)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:38][CH:37]=[CH:36][C:35]=4[C:34]2[C:43]4[C:30]([CH:31]=[C:32]5[CH:47]=[CH:46][CH:45]=[CH:44][C:33]5=2)=[CH:29][CH:28]=[CH:27][C:26]3=4)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:9][CH:10]=1

参加物

6

反応物 3

HCID 11430Potassium CarbonateHCID 69293Benzenamine, 4-methyl-N-(4-methylphenyl)-HCID 21910019Dibromobenzo[a]perylene

生成物 1

HCID 21910029Bis(di-p-tolylamino)benzo[a]perylene

試薬・触媒・溶媒 2

HCID 23978Copper触媒HCID 962Water溶媒

実験手順

Then, two equivalents of di-p-tolylamine, potassium carbonate, and copper power were added to the thus obtained dibromobenzo[a]perylene. This mixture stood still for reaction at 200 degrees centigrade for thirty hours. After reactant solution was diluted with water, reactant was extracted by chloroform. Thereafter, the reactant was refined in a conventional manner to thereby obtain bis(di-p-tolylamino)benzo[a]perylene.

後処理

  1. customThis mixture stood still for reaction at 200 degrees centigrade for thirty hours
  2. extractionwas extracted by chloroform

出典と根拠

ORDレコード
ord-0af6786593064068bc78cff2983b6753
出典データセット
uspto-grants-2006_10
特許番号
US07125614B2

反応ノート

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