Ammonia → 2-Amino-4-(3-chloropropyl)-6-trichloromethyl-1,3,5-triazine
反応式
[Cl:1][CH2:2][CH2:3][CH2:4][C:5]1[N:10]=[C:9]([C:11]([Cl:14])([Cl:13])[Cl:12])[N:8]=[C:7](C(Cl)(Cl)Cl)[N:6]=1.[NH3:19].O>O1CCCC1>[NH2:19][C:7]1[N:6]=[C:5]([CH2:4][CH2:3][CH2:2][Cl:1])[N:10]=[C:9]([C:11]([Cl:12])([Cl:13])[Cl:14])[N:8]=1参加物
5
実験手順
102.3 g of 2-(3-chloro-n-propyl)-4,6-bis-(trichloromethyl)-1,3,5-triazine are dissolved in 100 ml of tetrahydrofuran, and to this solution are added at room temperature, with stirring, 400 ml of concentrated aqueous ammonia solution. After 30 minutes, 500 ml of water are addded, and the reaction mixture is extracted twice with 100 ml of ether each time. The ether phases are dried over magnesium sulfate, filtered, and concentrated by evaporation to leave 68.3 g of title product in the form of light-brown oil.
後処理
- additionto this solution are added at room temperature
- extractionthe reaction mixture is extracted twice with 100 ml of ether each time
- dry with materialThe ether phases are dried over magnesium sulfate
- filtrationfiltered
- concentrationconcentrated by evaporation
出典と根拠
- ORDレコード
- ord-f347435542864956b4aaf97785a07137
- 出典データセット
- uspto-grants-1985_06
- 特許番号
- US04523947
反応ノート
読み込み中…