Sodium Sulfite → 4-Hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate

HRID 1248562

反応式

HRID 1248562 の反応式
[C:1](Cl)(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8].[CH3:13][C:14]([O:23][OH:24])([CH2:16][CH2:17][C:18]([CH3:22])([O:20]O)[CH3:19])[CH3:15].S([O-])([O-])=O.[Na+].[Na+]>>[C:1]([O:24][O:23][C:14]([CH3:15])([CH3:13])[CH2:16][CH2:17][C:18]([OH:20])([CH3:22])[CH3:19])(=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][C:7]([CH3:9])([CH3:8])[CH3:10]

参加物

4

反応物 3

HCID 24437Sodium SulfiteHCID 94502Neodecanoyl chlorideHCID 5204702,5-Dimethylhexane 2,5-dihydroperoxide

生成物 1

HCID 861185904-Hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate収率 55.1%

実験手順

Reacting neodecanoyl chloride with 2,5-dimethyl-2,5-dihydroperoxyhexane followed by reducing the intermediate product with a buffered sodium sulfite solution employing the same procedure as used in preparation of C-5 resulted in the preparation of 4-hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate. The liquid product had an assay of 91.7% and was obtained in a corrected yield of 55.1%. An infrared spectrum of the product showed a broad OH band centered at 3300 to 3500 cm-1.

後処理

  1. customas used in preparation of C-5

出典と根拠

ORDレコード
ord-f39b5f44f0104c6eb2d772c4c2aebbb7
出典データセット
uspto-grants-1985_06
特許番号
US04525308

関連ノート

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