Dimethylamine → HCID 12797674、化合物

HRID 1249113

反応式

HRID 1249113 の反応式
[CH3:1][NH:2][CH3:3].[Cl:4][C:5]1[CH:6]=[C:7]2[C:12](=[CH:13][CH:14]=1)[N:11]=[C:10]([O:15][C:16]1[CH:27]=[CH:26][C:19]([O:20][CH:21]([CH3:25])[C:22]([OH:24])=[O:23])=[CH:18][CH:17]=1)[CH:9]=[N:8]2>>[Cl:4][C:5]1[CH:6]=[C:7]2[C:12](=[CH:13][CH:14]=1)[N:11]=[C:10]([O:15][C:16]1[CH:17]=[CH:18][C:19]([O:20][CH:21]([CH3:25])[C:22]([OH:24])=[O:23])=[CH:26][CH:27]=1)[CH:9]=[N:8]2.[CH3:1][NH:2][CH3:3]

参加物

3

反応物 2

HCID 674DimethylamineHCID 178795Quizalofop

生成物 1

HCID 12797674HCID 12797674、化合物収率 91%

実験手順

In 30 ml. of 10% aqueous solution of dimethylamine, 3.4 g. (0.01 mole) of 2-[4-(6-chloro-2-quinoxalyloxy)phenoxy]propionic acid was added. After a dissolution, excess of dimethylamine and water were removed by evaporating them by a rotary evaporator and the residue was dried in vacuum to obtain 3.5 g. (yield: 91%) of a pale yellow object product having a melting point of 63° to 67° C.

後処理

  1. dissolutionAfter a dissolution
  2. customexcess of dimethylamine and water were removed
  3. customby evaporating them
  4. customby a rotary evaporator
  5. customthe residue was dried in vacuum
  6. customto obtain 3.5 g

出典と根拠

ORDレコード
ord-a32bfccf63e94fdaaa45716d226bb358
出典データセット
uspto-grants-1986_12
特許番号
US04629493

関連ノート

読み込み中…