1,2-Epoxycyclododeca-5,9-diene → Cyclododecanol

HRID 1250040ノート

反応式

HRID 1250040 の反応式
[O:1]1[CH:3]2[CH2:4][CH2:5][CH:6]=[CH:7][CH2:8][CH2:9][CH:10]=[CH:11][CH2:12][CH2:13][CH:2]12.[H][H]>[Pd]>[CH:2]1([OH:1])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

参加物

4

反応物 2

HCID 791351,2-Epoxycyclododeca-5,9-dieneHCID 178418361HCID 178418361、化合物

生成物 1

HCID 15595Cyclododecanol収率 5%

試薬・触媒・溶媒 1

HCID 23938Palladium触媒

実験手順

Also, the Drafted Report of 24th Symposium of Development in Reaction and Synthesis, Nov. 5 to 6, 1998, page 68, discloses a method of hydrogenating 1,2-epoxy-5,9-cyclododecadiene with hydrogen at ambient atmospheric pressure and room temperature in the presence of a catalyst comprising palladium carried on a carrier consisting of a carbon material. In this method, cyclododecanol was produced with a yield of 5% and no cyclododecanone was obtained.

後処理

  1. customAlso, the Drafted Report of 24th Symposium of Development in Reaction and Synthesis, Nov
  2. customat ambient atmospheric pressure and room temperature

出典と根拠

ORDレコード
ord-785d35ff3b6a41479bea5a07af8690e0
出典データセット
uspto-grants-2002_01
特許番号
US06335472B1

反応ノート

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