Ethoxydimethylsilane → Methacryloxyethoxypropyl dimethyl ethoxysilane

HRID 1252533

反応式

HRID 1252533 の反応式
[C:1]([O:6][CH2:7][CH2:8][O:9][CH2:10][CH:11]=[CH2:12])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH3:13][SiH:14]([CH3:18])[O:15][CH2:16][CH3:17]>[Pt]>[C:1]([O:6][CH2:7][CH2:8][O:9][CH2:10][CH2:11][CH2:12][Si:14]([CH3:18])([CH3:13])[O:15][CH2:16][CH3:17])(=[O:5])[C:2]([CH3:4])=[CH2:3]

参加物

4

反応物 2

HCID 61772Ethoxydimethylsilane2 回HCID 856092-Propenoic acid, 2-methyl-, 2-(2-propen-1-yloxy)ethyl ester

生成物 1

HCID 53895125Methacryloxyethoxypropyl dimethyl ethoxysilane

試薬・触媒・溶媒 1

HCID 23939Platinum触媒

反応条件

温度
50 °C

実験手順

The reaction vessel was a flask equipped with a stirring device, a thermometer, a dropping funnel and fitted with a reflux condenser and a drying tube. The flask charged with about one mole of allyloxyethyl methacrylate and about 1×10-5 moles of a platinum catalyst. The mixture heated to about 50° C. and maintained at 50° C. for 15 minutes. The temperature of the reaction mixture was cooled down to 20° C. with a water bath. When the temperature had reached 20° C., 1.1 moles of dimethylethoxysilane was added to the mixture with the temperature being held at 20° C. during dimethylethoxysilane addition, and stirred for 24 hours. Fractionation of the resulting gave methacryloxyethoxypropyl dimethyl ethoxysilane which had a vacuum boiling point of about 115° C. at 4 mm Hg.

後処理

  1. customequipped with a stirring device
  2. customa thermometer, a dropping funnel and fitted with a reflux condenser and a drying tube
  3. temperaturemaintained at 50° C. for 15 minutes
  4. temperatureThe temperature of the reaction mixture was cooled down to 20° C. with a water bath
  5. customhad reached 20° C.

出典と根拠

ORDレコード
ord-77b69d812a4b4284b3dfb1aca0f0d427
出典データセット
uspto-grants-1988_05
特許番号
US04743667

関連ノート

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