Chlorosulfonic acid → 2,1,3-Benzothiadiazole, 4-chlorosulfonyl-

HRID 1252851ノート

反応式

HRID 1252851 の反応式
[Cl:1][S:2]([OH:5])(=O)=[O:3].[N:6]1[S:7][N:8]=[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=12>>[N:6]1[S:7][N:8]=[C:9]2[C:14]([S:2]([Cl:1])(=[O:5])=[O:3])=[CH:13][CH:12]=[CH:11][C:10]=12

参加物

3

反応物 2

HCID 24638Chlorosulfonic acidHCID 675022,1,3-Benzothiadiazole

生成物 1

HCID 27354592,1,3-Benzothiadiazole, 4-chlorosulfonyl-

実験手順

To a stirred solution of 100 mL of chlorosulfonic acid at 0° C. was added 10.0 g of 2,1,3-benzothiadiazole under an inert atmosphere. The resulting mixture was heated at reflux for 30 minutes and cooled to room temperature. The reaction mixture was added dropwise to 1000 mL ice. The precipitates was collected, washed with water, and air dried to give the title compound as a beige solid, m.p. 146°-148° C.

後処理

  1. temperatureThe resulting mixture was heated
  2. temperatureat reflux for 30 minutes
  3. customThe precipitates was collected
  4. washwashed with water, and air
  5. customdried

出典と根拠

ORDレコード
ord-359c0f974ab24e28b1b1c0cbdc0b0171
出典データセット
uspto-grants-1988_05
特許番号
US04746356

反応ノート

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