(2-Aminobenzo[d]thiazol-6-yl)methanol → 2-Aminobenzo[d]thiazole-6-carbaldehyde

HRID 1253198ノート

反応式

HRID 1253198 の反応式
[NH2:1][C:2]1[S:3][C:4]2[CH:10]=[C:9]([CH2:11][OH:12])[CH:8]=[CH:7][C:5]=2[N:6]=1>C1COCC1.[O-2].[Mn+4].[O-2]>[NH2:1][C:2]1[S:3][C:4]2[CH:10]=[C:9]([CH:11]=[O:12])[CH:8]=[CH:7][C:5]=2[N:6]=1

参加物

4

反応物 1

HCID 13821540(2-Aminobenzo[d]thiazol-6-yl)methanol

生成物 1

HCID 138215412-Aminobenzo[d]thiazole-6-carbaldehyde

試薬・触媒・溶媒 2

HCID 178418406HCID 178418406、化合物触媒HCID 8028Tetrahydrofuran溶媒

実験手順

110.5 g (0.613 mol) of 1a are stirred in 200 ml of THF with 319.8 g (3.678 mol) of manganese (IV) oxide at room temperature for 3 days. The reaction mixture is filtered, the residue on the filter is washed with THF, and the filtrate is evaporated in vacuo.

後処理

  1. filtrationThe reaction mixture is filtered
  2. washthe residue on the filter is washed with THF
  3. customthe filtrate is evaporated in vacuo

出典と根拠

ORDレコード
ord-ca3210786c364083880abbc75021adba
出典データセット
uspto-grants-1988_05
特許番号
US04748163

反応ノート

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