Dilauryl Ether → 2-Methylundecane

HRID 1257509

反応式

HRID 1257509 の反応式
[CH2:1](O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]([CH3:12])[CH3:11].FC(F)(F)S(O)(=O)=O.C=CCCCCCCCC(C)C.C(OCCCCCCCCCCCC)CCCCCCCCCCC>>[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]([CH3:11])[CH3:12]

参加物

5

反応物 4

HCID 20667Dilauryl EtherHCID 62406Trifluoromethanesulfonic acidHCID 51994110-Methyl-1-undeceneHCID 6428591Isododecanol

生成物 1

HCID 234592-Methylundecane

実験手順

300.0 g Lial® 123 (isododecanol from Sasol) and 18.0 g trifluoromethanesulfonic acid (50% by weight in water) were introduced into a distillation apparatus and heated for 1.5 h to 240° C. The organic phase of the distillate obtained (171.9 g) was dried over sodium sulfate and the product was isolated by filtration). The product then contained 91.5% isododecene, 7.5% Lial® 123 and 1.0% didodecyl ether (GC analysis).

後処理

  1. temperatureheated for 1.5 h to 240° C
  2. customThe organic phase of the distillate obtained (171.9 g)
  3. dry with materialwas dried over sodium sulfate
  4. customthe product was isolated by filtration)

出典と根拠

ORDレコード
ord-48894196fe9f4034a9a0c2e7526108e1
出典データセット
uspto-grants-2013_06
特許番号
US08461407B2

関連ノート

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