Hexachloroacetone → N-alpha-naphthoyl-N'-trichloroacetylhydrazine
反応式
[Cl:1][C:2]([Cl:10])([Cl:9])[C:3](C(Cl)(Cl)Cl)=[O:4].[C:11]1([C:21]([NH:23][NH2:24])=[O:22])[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=[CH:13][CH:12]=1>C(#N)C>[C:11]1([C:21]([NH:23][NH:24][C:3](=[O:4])[C:2]([Cl:10])([Cl:9])[Cl:1])=[O:22])[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=[CH:13][CH:12]=1参加物
4
実験手順
To a mixture of 100 ml of acetonitrile and 14.6 g (0.055 mol) of hexachloroacetone was added 9.3 g of α-naphthoic acid hydrazide thus obtained and the resultant mixture was refluxed with stirring for 4 hours. The precipitates formed were recovered by filtration to provide 14.6 g (yield 88%) of N-α-naphthoyl-N'-trichloroacetylhydrazine.
後処理
- customthus obtained
- customThe precipitates formed
- filtrationwere recovered by filtration
出典と根拠
- ORDレコード
- ord-dfbeb1db28c1493cb7631e9785c63ea6
- 出典データセット
- uspto-grants-1981_07
- 特許番号
- US04279982
反応ノート
読み込み中…