Hydroquinone → Diethylene glycol monoacrylate

HRID 1282265ノート

反応式

HRID 1282265 の反応式
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[CH2:6]([OH:12])[CH2:7][O:8][CH2:9][CH2:10]O.[OH-].[K+].C1(C=CC(O)=CC=1)O>S(=O)(=O)(O)O>[C:1]([O:5][CH2:10][CH2:9][O:8][CH2:7][CH2:6][OH:12])(=[O:4])[CH:2]=[CH2:3]

参加物

6

反応物 4

HCID 785HydroquinoneHCID 6581Acrylic AcidHCID 8117Diethylene GlycolHCID 14797Potassium Hydroxide

生成物 1

HCID 61642Diethylene glycol monoacrylate

試薬・触媒・溶媒 1

HCID 1118Sulfuric Acid触媒

実験手順

Using 0.3 g (0.003 mole) of sulfuric acid as a catalyst, 72 g (1 mole) of acrylic acid was reacted with 106 g (1 mole) of diethylene glycol. The reaction mixture was neutralized with 0.34 g (0.006 mole) of potassium hydroxide, and 0.16 g (0.1 mass %) of hydroquinon was added as a stabilizer. Thus, diethylene glycol monoacrylate (A1-5) was obtained.

後処理

  1. additionwas added as a stabilizer

出典と根拠

ORDレコード
ord-8c4dc4ce9b38412cae8bf110bd46032d
出典データセット
uspto-grants-2002_09
特許番号
US06455606B1

反応ノート

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