Allyl Isothiocyanate → HCID 21519702、化合物
反応式
[C:1]([C:5]1[CH2:6][CH2:7][NH:8][CH2:9][CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[CH2:11]([N:14]=[C:15]=[S:16])[CH:12]=[CH2:13]>O1CCCC1>[CH2:11]([NH:14][C:15]([N:8]1[CH2:7][CH:6]=[C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[CH2:10][CH2:9]1)=[S:16])[CH:12]=[CH2:13]参加物
4
実験手順
In 20 ml. of anhydrous tetrahydrofuran there is dissolved 5.0 grams of 4-t-butyl-1,2,3,6-tetrahydropyridine, and with stirring there is added 3.5 grams of allylisothiocyanate in 10 ml of anhydrous tetrahydrofuran. The reaction mixture is stirred for 24 hours at room temperature and the tetrahydrofuran is evaporated in vacuo. The resulting solid is dried at 50°C/20 mmHg. to remove any unreacted allylisothiocyanate to give N-allyl-4-t-butyl-1,2,3,6- -tetrahydro-1-pyridinethiocarboxamide.
後処理
- stirringThe reaction mixture is stirred for 24 hours at room temperature
- customthe tetrahydrofuran is evaporated in vacuo
- customThe resulting solid is dried at 50°C/20 mmHg
- customto remove any unreacted allylisothiocyanate
出典と根拠
- ORDレコード
- ord-156cd34da4c54483b673ae5ca938c41d
- 出典データセット
- uspto-grants-1976_08
- 特許番号
- US03974283
反応ノート
読み込み中…