Adipic Acid → Diethyl Adipate
反応式
[C:1]([OH:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([OH:8])=[O:7].[CH2:11](N(CC)CC)[CH3:12].[CH2:18](OC(ON=C(C#N)C(N)=O)=O)[CH3:19]>O1CCCC1>[C:1]([O:10][CH2:18][CH3:19])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O:8][CH2:11][CH3:12])=[O:7]参加物
5
実験手順
To a solution of adipic acid (1.46 g) and triethylamine (2.8 ml) in tetrahydrofuran (30 ml), 2-ethoxycarbonyloxyimino-2-cyanoacetic acid amide (3.7 g) is added, and the resulting mixture is stirred at room temperature for 2 hours. The reaction mixture is treated as in Example A to give diethyl adipate (1.5 g) as an oil.
後処理
- additionThe reaction mixture is treated as in Example A
出典と根拠
- ORDレコード
- ord-60dc19e927b348b0a8b0c60d1d09524c
- 出典データセット
- uspto-grants-1976_08
- 特許番号
- US03976635
反応ノート
読み込み中…