Ethyl 2-methyl-4-pentenoate → Ethyl 2-methyl-3,4-pentadienoate

HRID 1283970ノート

反応式

HRID 1283970 の反応式
[CH2:1]([O:3][C:4](=[O:10])[CH:5]([CH3:9])[CH2:6][CH:7]=[CH2:8])[CH3:2].C(OC(=O)C(C)/C=C\C)C>[Pd].C([O-])([O-])=O.[Ca+2]>[CH2:1]([O:3][C:4](=[O:10])[CH:5]([CH3:9])[CH:6]=[C:7]=[CH2:8])[CH3:2]

参加物

4

反応物 2

HCID 62024Ethyl 2-methyl-4-pentenoateHCID 14423335Ethyl 2-methyl-3-pentenoate, (3Z)-

生成物 1

HCID 62166Ethyl 2-methyl-3,4-pentadienoate

試薬・触媒・溶媒 1

HCID 12000666Calcium Palladium Carbonate触媒

実験手順

FIG. 7 is an illustration of the GLC curve for a mixture of ethyl-2-methyl-4-pentenoate and ethyl-2-methyl-cis-3-pentenoate produced by the hydrogenation of ethyl-2-methyl-3,4-pentadienoate with a Pd/CaCO3 catalyst according to Example XVII.

出典と根拠

ORDレコード
ord-5537eb32f8cb4a83942683e92bd4d351
出典データセット
uspto-grants-1976_08
特許番号
US03976801

反応ノート

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