4-Bromophenol → p-Bromo-(1-methoxyethoxy)benzene

HRID 129365

反応式

HRID 129365 の反応式
[CH:1]1[C:6]([OH:7])=[CH:5][CH:4]=[C:3]([Br:8])[CH:2]=1.[CH:9]([O:11][CH3:12])=[CH2:10]>>[Br:8][C:3]1[CH:4]=[CH:5][C:6]([O:7][CH:9]([O:11][CH3:12])[CH3:10])=[CH:1][CH:2]=1

参加物

3

反応物 2

HCID 78084-BromophenolHCID 7861Methyl vinyl ether

生成物 1

HCID 22908633p-Bromo-(1-methoxyethoxy)benzene収率 90%

実験手順

Using p-bromophenol (17.3 g, 0.1 mole) and methyl vinyl ether (14.0 g, 0.2 mole), the reaction was carried out in the same manner as described in Synthesis Example 1, (1), and the crude oil (24 g) was purified by distillation under reduced pressure to afford 20.8 g of p-bromo-(1-methoxyethoxy)benzene as a pale yellow oil having a boiling point 89-90° C./2 mmHg.

後処理

  1. customas described in Synthesis Example 1, (1),
  2. distillationthe crude oil (24 g) was purified by distillation under reduced pressure

出典と根拠

ORDレコード
ord-24808c6fb6474ee0bab5996c316c4c25
出典データセット
uspto-grants-1995_11
特許番号
US05468589

関連ノート

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