Aluminum nitrate → Aluminium tris(2,4,6-tris(dimethylaminomethyl)phenolate)

HRID 129902ノート

反応式

HRID 129902 の反応式
[CH3:1][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:14])[CH3:13])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:3].[Na+].[N+]([O-])([O-])=O.[Al+3:25].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O>C(O)CCC>[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[CH3:3][N:2]([CH2:4][C:5]1[CH:10]=[C:9]([CH2:11][N:12]([CH3:13])[CH3:14])[CH:8]=[C:7]([CH2:15][N:16]([CH3:18])[CH3:17])[C:6]=1[O-:19])[CH3:1].[Al+3:25]

参加物

4

反応物 2

HCID 26053Aluminum nitrateHCID 23711567Sodium 2,4,6-tris(dimethylaminomethyl)phenolate

生成物 1

HCID 67805376Aluminium tris(2,4,6-tris(dimethylaminomethyl)phenolate)

試薬・触媒・溶媒 1

HCID 2631-Butanol溶媒

実験手順

20 g (0.069 mol) of sodium 2,4,6-tris(dimethylaminomethyl)phenolate and 57.1 g of 1-butanol are placed in a 100 ml round-bottomed flask having a magnetic stirrer, and then 8.70 g (0.023 mol) of aluminium nitrate are added. The solution is stirred for 2 hours, and then the precipitated sodium nitrate is filtered off. A clear, brown 25% accelerator solution of aluminium tris(2,4,6-tris(dimethylaminomethyl)phenolate) in 1-butanol is obtained.

後処理

  1. filtrationthe precipitated sodium nitrate is filtered off

出典と根拠

ORDレコード
ord-99313379c6d5489481226546473cd6d6
出典データセット
uspto-grants-1995_11
特許番号
US05470896

反応ノート

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