2-Acetylnaphthalene → 4,4,5,5,6,6,6-Heptafluoro-1-(2-naphthyl)hexane-1,3-dione

HRID 130298

反応式

HRID 130298 の反応式
[C:1]([C:4]1[CH:13]=[CH:12][C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=1)(=[O:3])[CH3:2].[F:14][C:15]([F:28])([F:27])[C:16]([F:26])([F:25])[C:17]([F:24])([F:23])[C:18](OCC)=[O:19]>>[F:23][C:17]([F:24])([C:16]([F:25])([F:26])[C:15]([F:14])([F:27])[F:28])[C:18](=[O:19])[CH2:2][C:1]([C:4]1[CH:13]=[CH:12][C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=1)=[O:3]

参加物

3

反応物 2

HCID 71222-AcetylnaphthaleneHCID 9644Butanoic acid, 2,2,3,3,4,4,4-heptafluoro-, ethyl ester

生成物 1

HCID 860043274,4,5,5,6,6,6-Heptafluoro-1-(2-naphthyl)hexane-1,3-dione

実験手順

The compound was synthesized according to example 1 using 2-acetylnaphthalene and ethyl heptafluorobutyrate as starting materials. The product was crystallized from petroleum ether. 1H NMR (CDCl3): 6.76 (s, 1 H); 7.57-7.66 (m, 2H); 7.90 (bd, 1 H); 7.93-7.94 (m, 2H); 7.98 (bd, 1 H); 8.53 (s, 1H). IR (film): 1602 (C═O); 1232 (C—F).

後処理

  1. customThe compound was synthesized
  2. customThe product was crystallized from petroleum ether

出典と根拠

ORDレコード
ord-ed593dcb2091417f8386ebc40775ec71
出典データセット
uspto-grants-2008_06
特許番号
US07381567B2

関連ノート

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