Formic Acid → 1,2-Dodecanediol
反応式
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]C.[CH:13]([OH:15])=O.[OH:16]O>C(O)C>[CH2:13]([OH:15])[CH:11]([OH:16])[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]参加物
5
実験手順
336 g (2.00 mol) of 1-dodecene were reacted with 236 g of formic acid and 185 g of a 50% strength aqueous H2O2 solution in accordance with Example 4. 412 g of ethanol were employed for the Marlon AS3 acid-catalyzed transesterification, and the main fraction obtained after the workup by distillation was 99.5% pure, virtually odorless 1,2-dodecanediol.
後処理
- customthe main fraction obtained after the workup
- distillationby distillation
出典と根拠
- ORDレコード
- ord-e3f2b7809e3f48e28f4d2541ab2247dc
- 出典データセット
- uspto-grants-2008_06
- 特許番号
- US07385092B2
反応ノート
読み込み中…